Ch 11: Ethers, Epoxides, and Sulfides

  1. Ethers
    1. Nomenclature
    2. Properties
    3. Preparations
      1. Two methods dehydration of alcohols & additon of alcohols to alkenes
      2. Williamson ether synthesis
    4. Reactions
  2. Epoxides
    1. Nomenclature
    2. Preparations
      1. Intramolecular Williams synthesis
      2. Use of peroxyacids
    3. Reactions
      1. Acid-catalyzed ring opening
      2. Nucleophilic ring opening
      3. Sample use of an epoxide in synthesis
  3. Sulfides
  4. Crown ethers
    1. Structures and use
    2. Supramolecular chemistry
  5. Protection/deprotection of Alcohols

Skip Section 8.D (Sharpless Epoxidation)